Full metadata record
DC pole | Hodnota | Jazyk |
---|---|---|
dc.contributor.author | Nešpůrek, Stanislav | |
dc.contributor.author | Kuberský, Petr | |
dc.contributor.author | Polanský, Radek | |
dc.contributor.author | Trchová, Miroslava | |
dc.contributor.author | Šebera, Jakub | |
dc.contributor.author | Sychrovský, Vladimír | |
dc.date.accessioned | 2022-02-28T11:00:25Z | - |
dc.date.available | 2022-02-28T11:00:25Z | - |
dc.date.issued | 2022 | |
dc.identifier.citation | NEŠPŮREK, S. KUBERSKÝ, P. POLANSKÝ, R. TRCHOVÁ, M. ŠEBERA, J. SYCHROVSKÝ, V. Raman spectroscopy and DFT calculations of PEDOT:PSS in a dipolar field. PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2022, roč. 24, č. 1, s. 541-550. ISSN: 1463-9076 | cs |
dc.identifier.issn | 1463-9076 | |
dc.identifier.uri | 2-s2.0-85121864296 | |
dc.identifier.uri | http://hdl.handle.net/11025/47034 | |
dc.format | 10 s. | cs |
dc.format.mimetype | application/pdf | |
dc.language.iso | en | en |
dc.publisher | Royal Society of Chemistry | en |
dc.relation.ispartofseries | Physical Chemistry Chemical Physics | en |
dc.rights | © the Owner Societies | en |
dc.title | Raman spectroscopy and DFT calculations of PEDOT:PSS in a dipolar field | en |
dc.type | článek | cs |
dc.type | article | en |
dc.rights.access | closedAccess | en |
dc.type.version | publishedVersion | en |
dc.description.abstract-translated | The conductive polymer-electrolyte interface plays an important role in many electrochemical devices. An unusual situation arises when a solvent-free ionic liquid (SF-IL) is used as the electrolyte because it behaves as a molten salt rather than an electrolyte solution. On the basis of Raman spectra, it was found that the presence of ion pairs of SF-IL in the vicinity of poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) results in a decrease in the oxidation level of the polymer and an increase in the HOMO-LUMO gap. The process of polymer “dedoping” and the modification of the electronic structure of the polymer are illustrated by quantum chemical calculations. | en |
dc.subject.translated | chemical modification | en |
dc.subject.translated | electronic structure | en |
dc.subject.translated | ionic liquids | en |
dc.subject.translated | polyelectrolytes | en |
dc.subject.translated | quantum chemistry | en |
dc.identifier.doi | 10.1039/d1cp03899k | |
dc.type.status | Peer-reviewed | en |
dc.identifier.document-number | 729859200001 | |
dc.identifier.obd | 43934716 | |
dc.project.ID | GA20-03913S/Organické senzory plynů - nové struktury, jejich vlastnosti a funkce | cs |
Vyskytuje se v kolekcích: | Články / Articles (KET) OBD |
Soubory připojené k záznamu:
Soubor | Velikost | Formát | |
---|---|---|---|
Nespurek et al. - 2022 - Raman spectroscopy.pdf | 5,89 MB | Adobe PDF | Zobrazit/otevřít Vyžádat kopii |
Použijte tento identifikátor k citaci nebo jako odkaz na tento záznam:
http://hdl.handle.net/11025/47034
Všechny záznamy v DSpace jsou chráněny autorskými právy, všechna práva vyhrazena.