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dc.contributor.authorVakili, Mohammadtaghi
dc.contributor.authorGholami, Fatemeh
dc.contributor.authorZwain, Haider M.
dc.contributor.authorWang, Wei
dc.contributor.authorMojiri, Amin
dc.contributor.authorTomáš, Martin
dc.contributor.authorCagnetta, Giovanni
dc.contributor.authorGholizadeh, Reza
dc.contributor.authorDastyar, Wafa
dc.contributor.authorGholami, Zahra
dc.date.accessioned2023-10-16T10:00:10Z-
dc.date.available2023-10-16T10:00:10Z-
dc.date.issued2023
dc.identifier.citationVAKILI, M. GHOLAMI, F. ZWAIN, HM. WANG, W. MOJIRI, A. TOMÁŠ, M. CAGNETTA, G. GHOLIZADEH, R. DASTYAR, W. GHOLAMI, Z. Removal of GenX by APTES functionalized diepoxyoctane cross-linked chitosan beads. Journal of Environmental Chemical Engineering, 2023, roč. 11, č. 5, s. nestránkováno. ISSN: 2213-2929cs
dc.identifier.issn2213-2929
dc.identifier.uri2-s2.0-85164213467
dc.identifier.urihttp://hdl.handle.net/11025/54405
dc.format
dc.format11 s.cs
dc.format.mimetypeapplication/pdf
dc.language.iso
dc.language.isoenen
dc.publisherElsevieren
dc.relation.ispartofseriesJournal of Environmental Chemical Engineeringen
dc.rightsPlný text je přístupný v rámci univerzity přihlášeným uživatelůmcs
dc.rights© Elsevieren
dc.titleRemoval of GenX by APTES functionalized diepoxyoctane cross-linked chitosan beadsen
dc.typečlánekcs
dc.typearticleen
dc.rights.accessrestrictedAccessen
dc.type.versionpublishedVersionen
dc.description.abstract-translatedPerfluoro-2-propoxypropanoic acid ammonium salt, commonly known as GenX, is a persistent, bioaccumulative, and toxic synthetic organofluorine compound utilized in producing various products. It has become a concern due to its extensive presence in the aquatic environment and its resistance to conventional water treatment methods. This study achieved effective adsorption of GenX by employing chitosan (CS) modified adsorbent. Cross-linked and aminated CS beads were synthesized using 1,2:7,8-diepoxyoctane (DEO) and 3-aminopropyl triethoxysilane (APTES). The prepared CS-DEO-APTES adsorbent exhibited an adsorption capacity of 825.9 mg/g, which was 2.26 times higher than that of CS beads (364.6 mg/g), attributed to its higher content of amino groups. Additionally, the CS-DEO-APTES adsorbent demonstrated excellent stability under acidic conditions (optimal pH= 4) due to the cross-linking process. Kinetic data, following a pseudo-second-order rate and isothermal data, fitting well with the Langmuir model, indicated that the interactions between GenX and CS-DEO-APTES were chemisorptive, with a nearly uniform distribution of adsorption sites. GenX-saturated beads were successfully regenerated for at least 6 cycles using a 1 % w/v aqueous NaCl and methanol solution (30:70 % v/v). Density functional theory (DFT) calculations suggested that electrostatic interactions primarily influence the adsorption of GenX. These results highlight the effectiveness of the CS-DEO-APTES adsorbent as a viable option for removing GenX from aqueous solutions.en
dc.subject.translatedadsorption; aminationen
dc.subject.translatedchitosan beadsen
dc.subject.translatedcross-linkingen
dc.subject.translatedGenXen
dc.subject.translatedperfluoro-2-propoxypropanoic acid ammonium salten
dc.identifier.doi10.1016/j.jece.2023.110539
dc.type.status
dc.type.statusPeer-revieweden
dc.identifier.document-number1041180200001
dc.identifier.obd43940010
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